[en] Thioantimonate compounds of [Mn(en)₃]₂Sb₂S₅ (1) and [Ni(en)₃(Hen)]SbS₄ (2) (en=ethylenediamine) were prepared by reaction of transition metal chloride with Sb and S₈ powders under solvothermal conditions. Compound 1 consists of discrete [Sb₂S₅]^4- anion, which is formed by corner-sharing SbS₃ trigonal pyramids. Compound 2 is composed of discrete tetrahedral [SbS₄]^3- anion. The compounds 1 and 2 are charge compensated by [M(en)₃]²⁺ cations, whereas in the crystal of 2 there is another counter ion of [Hen]⁺. The results of the synthesis suggest that the temperature, the concentration and the existing states of the starting materials and so on are important for the structure and composition of the final products. In addition, the oxidation-state of antimony might be related to the molar ratio of the reactants. Excess amount of elemental S is beneficial to the higher oxidation-state of thioantimonate (V). Compound 1 decomposes from 150 deg. C to 350 deg. C, while compound 2 decomposes from 200 deg. C to 350 deg. C remaining Sb₂S₃ and NiSbS as residues

[en] By micromagnetic simulation, we investigated a double 360° domain walls system in two parallel nanowires. Two domain walls are coupled to each other via magnetostatic interaction. When a spin-polarized current is applied to only one nanowire or both nanowires with the same direction, the two domain walls propagate along nanowires together. The critical velocity of such system is obviously higher than that of a single 360° domain wall. The interaction between the two domain walls can be modeled as two bodies that connected by a spring, and we analyzed the coupling characteritics of the double 360° domain walls at last

[en] With the development of society and economy, more and more automobile and vehicle run in the various roads. Car tail gas can not only pollute the air, but also can still result in the pollution of soil and ground water even underground water. Soil pollution coming from car tail gas is investigated in detail by experimental detection by Geofina Hydrocarbon Meter (GHM) made in Norway in this paper. Experiment samples are collected from thruway and highway side, and the organic pollutants of the samples are analyzed by the GHM instrument. Experiment shows that various kinds of organic pollutants are found in the samples, such as 14 species normal alkanes, 25 species aromatics, 13 species heteocycle compounds and 9 species phenols and so on. The characteristics of organic pollution resulted from car tail gas in the soil are obtained by detection analysis. The soil pollution caused by car tail gas has heavy toxicity to human being and the natural entironment. Consequently, organic contamination in the soil by the tail gas can't be neglected. The relevant investigation should be made so that some precautionary and cure measures may be proposed as soon as possible