AbstractAbstract
[en] In this work are studied the different types of aging; they are classified according to the external effects at which they are submitted to: high temperature for a thermal aging; UV or ionizing radiations for the photochemical or radiochemical aging; hydrolysis, oxidation, ozonolysis or mechanical stress for the chemical aging; living organisms for the biochemical aging. (O.M.)
Original Title
Plastochimie. Differents types de vieillissement chimique des plastiques
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15 refs.
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Journal Article
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Techniques de l'Ingenieur. Plastiques; ISSN 0245-9574; ; v. AM1(AM86); p. AM3152.1-AM3152.14
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CHEMICAL ANALYSIS, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, DECOMPOSITION, ELECTROMAGNETIC RADIATION, GRAVIMETRIC ANALYSIS, KINETICS, LYSIS, MATERIALS, NUCLEAR FACILITIES, ORGANIC COMPOUNDS, ORGANIC POLYMERS, PETROCHEMICALS, PETROLEUM PRODUCTS, PHOTOCHEMICAL REACTIONS, POLYMERS, POWER PLANTS, QUANTITATIVE CHEMICAL ANALYSIS, RADIATION EFFECTS, RADIATIONS, REACTION KINETICS, SOLVOLYSIS, SYNTHETIC MATERIALS, THERMAL ANALYSIS, THERMAL POWER PLANTS, THERMOCHEMICAL PROCESSES
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AbstractAbstract
[en] The industrial use of ionizing radiations (beta and gamma), initially for the sterilization of medico-surgical instruments and for the preservation of food products, has led to the development of the chemistry of polymers under radiations. Ionizing radiations can initiate chemical reactions (chain cutting, poly-additions, polymerization etc..) thanks to the formation of free radicals. The main applications concerns the degradation of plastics, the reticulation of plastics and of woods impregnated with resin, and the grafting of polymers. The processing of plastic materials was initially performed with low energy electron accelerators (0.1 to 3 MeV), allowing only surface treatments, while recent high energy accelerators (10 MeV) and gamma facilities allow the treatment in depth of materials (from few cm to 1 m). This article describes the industrial treatments performed with such high energy facilities: 1 - action of ionizing radiations on plastic materials: different types of ionizing radiations, action of beta and gamma radiations, chemical changes induced by beta and gamma radiations; 2 - reticulation of plastic materials submitted to beta and gamma radiations: radio-'reticulable' polymers and reticulation co-agents, modification of the properties of reticulated plastic materials under beta and gamma radiations; 3 - industrial aspects of reticulation under beta and gamma radiation: industrial irradiation facilities, dosimetry and radio-reticulation control, applications; 4 - conclusion. (J.S.)
Original Title
Modifications physico-chimiques des plastiques par ionisation
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Record Type
Journal Article
Journal
Techniques de l'Ingenieur. Plastiques et Composites; ISSN 0245-9574; ; v. AM1(AM87); p. AM3039.1-AM3039.10
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