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Aldred, A.T.; Dunlap, B.D.; Lander, G.H.
Argonne National Lab., Ill. (USA)1976
Argonne National Lab., Ill. (USA)1976
AbstractAbstract
[en] This paper reviews recent high-field (up to 80 kOe) magnetization, nuclear-gamma-ray resonance, and neutron diffraction measurements on a number of actinide ferromagnets with the C-15 Laves phase crystal structure. NpAl2 and NpOs2 are an interesting contrast; NpAl2 behaves as a localized 5f system whereas NpOs2 exhibits properties usually associated with itinerant ferromagnets. The second part of the paper reports similar measurements on the series AnFe2, where An = U, Np, Pu, and Am. The properties of these compounds suggest an increasing localization of 5f electrons as one proceeds from uranium to americium. The Pu ion in PuFe2 is definitely trivalent 5f5, but the observation of a small negative moment on the Am site in AmFe2 implies a partial occupancy of the Am2+ 5f7 state in this compound. This is the first indication of a mixed valence configuration in an actinide system
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1976; 10 p; 2. international conference on the electronic structures on the actinides; Wroclaw, Poland; 13 Sep 1976; Available from NTIS. $3.50.
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