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Dorogova, M.; Paul-Boncour, V.; Pavlyuk, V.; Solokha, P.
CEA Saclay, 91 - Gif-sur-Yvette (France). INSTN, Institut National des Sciences et Techniques Nucleaires2007
CEA Saclay, 91 - Gif-sur-Yvette (France). INSTN, Institut National des Sciences et Techniques Nucleaires2007
AbstractAbstract
[en] Complete text of publication follows: The purpose of the current work was to synthesize and investigate the hydrogen storage properties of ternary alloys from RE-M-Mg systems (RE-rare earth metals, M - transition element such as Ni and Cu). Alloys based on magnesium are known to store high amount of hydrogen (up to 7.7 wt.%) reversibly. Mg2Ni-based alloys offer also very high capacity (up to 4 wt.% H2). This storage capacity coupled with a low price and reversibility suggests that magnesium and magnesium-based alloys could be advantageous for use in battery electrodes and gaseous - hydrogen storage systems. Therefore, Mg-based and Mg2Ni-based materials were in the focus of our studies. The REMg2Cu9 ternary compounds (where RE - Y, La-Nd, Sm-Ho, Yb) [1] and REMg2(CuNi)9 alloys (where RE = La, Tb, Pr) were synthesised. Crystal structure determination and microstructural characterisation were performed. LaMg2Cu9, TbMg2Cu9, PrMg2Cu9, LaNi5Cu4Mg2 and TbNi3Cu6Mg2 were chosen for the investigation of hydrogen storage properties. TbMg2Cu9 and PrMg2Cu9 did not absorb hydrogen in pressure range 1 to 10 bar and at the ambient temperature. LaMg2Cu9 absorbs 3 H/f.u (1.004 wt%) under 100 bar and at 25 C. LaMg2Cu4Ni5 absorbs 1.6 H/f.u (1.002 wt%) under 10 bar and at 25 C. Pressure - hydrogen concentration isotherm was measured. TbMg2Ni3Cu6 absorbs 3 H/f.u (1.004 wt%) under 100 bar and at 25 C. All the samples needed to be activated by heat treatment under vacuum followed by several absorption - desorption cycles
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2007; 1 p; Colloquium 'Materials, Mechanics, Microstructure: hydrogen in materials'; Colloque 'Materiaux, Mecanique, Microstructure: L'hydrogene dans les materiaux'; Saclay (France); 18-19 Jun 2007; 1 ref.
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