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AbstractAbstract
[en] The effects of oxidizing atmosphere and temperature on the reactivities and strengths of PGX, H451, and IG-11 were examined. Preliminary measurements of the oxidation kinetics of these graphites in H2O-, CO2- and O2-containing atmospheres indicated that the reactivities of H451 graphite toward O2 and H2O are quite similar to those of IG-11 graphite. The apparent activation energy for oxidation of these in O2 were estimated to be approx. 175 kJ/mol while that in H2O is probably approx. 200 kJ/mol. The apparent activation energy of IG-11 graphite oxidized in CO2 is 255 +- 18 kJ/mol. PGX graphite was found to be quite variable in its reactivity toward H2O. A linear dependence with [Fe] was determined, but other intrinsic properties were found to affect its absolute reactivity by as much as a factor of X50
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Sep 1981; 75 p; BNL-NUREG--51493; Available from NTIS., PC A04/MF A01 as DE82008456
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