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AbstractAbstract
[en] This report discusses in a quantitative manner the evolution of the near field aqueous chemistry as a result of the interactions between three different intruding groundwaters (Aespoe, Gideaa and Finnsjoen) with the MX-80 bentonite buffer material. The main emphasis has been placed on studying the evolution of the main chemical buffers of the system (alkalinity and redox capacities) and the resulting master variables (pH and pe). The calculations have been done by using a set of thermodynamic and kinetic parameters previously calibrated against experimental data on bentonite/granitic groundwater interactions, in combination with the PHREEQC geochemical code. The results of the calculations indicate that the alkalinity buffer capacity is mainly exerted by the accessory content of carbonate minerals (calcite) in the bentonite system, while the ion exchange process plays a secondary (but not negligible) role. The Ca(II) content of the intruding groundwater has an impact on the resulting pH. For Ca(II) rich waters, like Aespoe, the resulting pH remains in the range of granitic groundwaters (7.5-9.5) during the overall repository lifetime (1 million years). For Ca(II) poor groundwaters, the systems evolves to high alkalinity (pH : 10.5 - 10.8) due to the depletion of calcite and the release of carbonate in to the near field aqueous chemistry. Concerning the reducing capacity of the system, this is mainly controlled by the accessory pyrite content, although the Fe(II) content in montmorillonite and in the carbonates cannot be disregarded. Reducing conditions in the bentonite/groundwater system are ensured throughout the lifetime of the repository system unless this is placed in direct and lifetime contact with the atmosphere (surface storage)
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Dec 1999; 56 p; ISSN 1404-0344; ; 17 refs, 24 figs, 9 tabs
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