AbstractAbstract
[en] During the past year the research under the contract has evolved along several lines consistent with the goal of achieving a better understanding of the interaction of molecules. First, was developed appropriate theoretical collision techniques and then implementation for practical systems of interest. This activity emphasized the determination of key physical factors controlling inelastic collision behavior. Also new methods were developed for inverting experimental relaxation data to yield detailed state-to-state rate constants. In addition a new effort was undertaken to develop efficient sensitivity analysis techniques for probing parameter dependencies in chemical kinetics systems. In summary, research on the following topics was pursued: physical analysis of atom-symmetric top collisions, vibration-rotation inelastic collisions in the CO-He System, collisional excitation of interstellar molecules: H2, sensitivity analysis in quantum dynamics, correlation of relaxation data: application to (A1Sigma/sub u/)Na2*-Xe, vibrational-rotational relaxation from high vibrational state, in He-HD, the Green's function method of sensitivity analysis in chemical kinetics, and the classical path approximation in time-dependent quantum collision theory. The essence of these various activities is described in the body of this report. The publications resulting from this research contain further detailed information, and these papers are listed at the end of the report
Original Title
Summaries of research activities at Princeton Univ
Primary Subject
Source
1978; 18 p; Available from NTIS., PC A02/MF A01
Record Type
Report
Literature Type
Progress Report
Report Number
Country of publication
Descriptors (DEI)
ATOM COLLISIONS, CARBON MONOXIDE, CHEMICAL REACTION KINETICS, CORRELATIONS, EXCITATION, GREEN FUNCTION, HELIUM, HYDROGEN, HYDROGEN DEUTERIDE, INELASTIC SCATTERING, MOLECULE COLLISIONS, QUANTUM MECHANICS, RELAXATION, RESEARCH PROGRAMS, ROTATIONAL STATES, SODIUM, SYMMETRY, TIME DEPENDENCE, VIBRATIONAL STATES, XENON
Descriptors (DEC)
ALKALI METALS, CARBON COMPOUNDS, CARBON OXIDES, CHALCOGENIDES, COLLISIONS, DEUTERIUM COMPOUNDS, ELEMENTS, ENERGY LEVELS, ENERGY-LEVEL TRANSITIONS, EXCITED STATES, FUNCTIONS, HYDROGEN COMPOUNDS, KINETICS, MECHANICS, METALS, NONMETALS, OXIDES, OXYGEN COMPOUNDS, RARE GASES, REACTION KINETICS, SCATTERING
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