AbstractAbstract
[en] Progress reports are presented for the following research topics: reaction of chlorofluoromethyl radicals, CF2Cl, with O2; kinetics of highly vibrational excited molecules; kinetics of CH2(1B1) reactions; and flash photolysis with time resolved mass spectroscopy. Some of the highlights are: (1) information on the mechanism of the reaction of CF2Cl radicals has been obtained, including evidence that CF2ClO radicals can oxidize CO; (2) CF2Cl radicals were produced by photooxidation of 1,3-dichlorotetrafluoroacetone (DTA) at 313 nm; (3) investigation of the DTA-O2 photolysis system using flash spectroscopy continued and observations are summarized; (4) results from laser flash photolysis-absorption spectroscopy show that collisional deactivation of toluene, ethylcycloheptatriene and isopropylcycloheptatriene occurs by removal of relatively small amounts of energy; (5) flashlamp pumped dye laser was used as a 400 nm excitation source to photolyze diazomethane, CH2N2. The photon energy was sufficient to produce the second excited state of methylene, CH2(1B1)
Original Title
CF2Cl, CF2ClO
Primary Subject
Source
1982; 13 p; Available from NTIS, PC A02/MF A01 as DE83001646
Record Type
Report
Literature Type
Progress Report
Report Number
Country of publication
Descriptors (DEI)
Descriptors (DEC)
AMPLIFIERS, CARBON COMPOUNDS, CARBON OXIDES, CHALCOGENIDES, CHEMICAL REACTIONS, DECOMPOSITION, ELECTROMAGNETIC RADIATION, ELEMENTS, ENERGY LEVELS, EQUIPMENT, KINETICS, LASERS, NONMETALS, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, RADIATIONS, REACTION KINETICS, SPECTROSCOPY
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