Application of the method of heterogeneous equilibrium between solid and liquid phases for study of actinoids in the lowest oxidation states
AbstractAbstract
[en] Cocrystallization of Fmsup(2+) and Md+ with NaCl and KCl in aqueous-ethanol solutions in the presence of bivalent lanthanides is investigated. On the basis of thermodynamic study of the cocrystallization results it has been ascertained, that at the redox potential of Eusup(2+) mendelevium is reduced to oxidation state 1+ and it is cocrystallized with KCl and NaCl due to isomorphous cocrystallization. Fermium in the same medium is reduced by Smsup(2+) only to the oxidation state 2+ and forms anomalously mixed crystals (AMC) withKCl,at that, its cocrystallization coefficient increases linearly with Cl- concentration increase inagreement with calculation. The dependences established show, that Md*H+ and Fmsup(2+) do not form stable chloride complexes and in this respect they are analogs of alkali and alkaline earth ions. The study of Md+ withSmF2 and YbF2 cocrystallization has shown, that in the systems AMC are formed in a similar way toAg+ cocrystallization with SrF2
Original Title
Primenenie metoda geterogennogo ravnovesiya mezhdu tverdoj i zhidkoj fazami dlya izucheniya aktinoidnykh ehlementov v nizshikh sostoyaniyakh okisleniya
Source
For English translation see the journal Soviet Radiochemistry (USA).
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Journal Article
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Descriptors (DEC)
ACTINIDE COMPOUNDS, ALCOHOLS, ALKALI METAL COMPOUNDS, CHLORIDES, CHLORINE COMPOUNDS, DISPERSIONS, HALIDES, HALOGEN COMPOUNDS, HOMOGENEOUS MIXTURES, HYDROXY COMPOUNDS, MIXTURES, ORGANIC COMPOUNDS, PHASE TRANSFORMATIONS, POTASSIUM COMPOUNDS, SODIUM COMPOUNDS, SOLUTIONS, TRANSPLUTONIUM COMPOUNDS, TRANSURANIUM COMPOUNDS
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