[en] Electron and IR absorption spectra of sublimated PcZrTpypa layers (zirconium complex with phthalocyanine and tetra-2,3-pyridineporphyrazine ligands) were obtained. It is shown that monocationic PcZrTpypa salts form during layer interaction with iodine vapors. It is concluded that electronic structure of molecule and PcZrTpypa cations is simmetrical about complexing Zr atom