Compressive creep behavior of Nb5Si3
AbstractAbstract
[en] Advanced intermetallic materials, such as refractory silicides, exhibit high melting points, high stiffness, low densities, and good strength retention at elevated temperatures. Further, some of these silicides are in equilibrium with terminal refractory solid solution (beta) phases, and therefore, offer the potential for ductile phase toughening. Studies were conducted to elucidate the compressive creep behavior of monolithic Nb5Si3 and to generate the constitutive creep law. This, in turn, is required for modeling the creep behavior of the Nb/Nb5Si3 two-phase system. Nb5Si3 has the ordered tetragonal structure with 32 atoms/cell in both its allotropic forms: αNb5Si3 (D8l Cr5Si3-type; a ∼ 0.656 nm; c = 1.187 nm) and βNb5Si3 (D8m W5Si3-type; a = 1.000 nm; c = 0.507 nm). αNb5Si3 is stable below 1,935 C, while βNb5Si3 is stable above 1,645 C. The large lattice parameters as well as the large number of atoms in the unit cell suggest that dislocation creep is unlikely to occur in Nb5Si3, because large Burgers vectors and complex dislocation core structures are expected in this material
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