Long-term test results from a West Valley actinide-doped reference glass
Fortner, J.A.; Gerding, T.J.; Bates, J.K.
Argonne National Lab., IL (United States). Funding organisation: USDOE, Washington, DC (United States)1995
Argonne National Lab., IL (United States). Funding organisation: USDOE, Washington, DC (United States)1995
AbstractAbstract
[en] Results from drip tests designed to simulate unsaturated conditions in the proposed Yucca Mountain Repository are reported for an actinide-doped glass (reference glass ATM-10) used as a model waste form. These tests have been ongoing for nearly 7 years, with data collected on solution composition (including transuranics), colloid formation and disposition, glass corrosion layers, and solid secondary phases. This test is unique because of its long elapsed time, high content of thorium and transuranics, use of actual groundwater from the proposed site area, use of contact between the glass and sensitized stainless steel in the test, and the variety of analytical procedures applied to the components. Some tests have been terminated, and scanning electron microscopy (SEM) and analytical transmission electron microscopy (AEM) were used to directly measure glass corrosion and identify secondary phases. Other tests remain ongoing, with periodic sampling of the water that had contacted the glass. The importance of integrated testing has been demonstrated, as complex interactions between the glass, the groundwater, and the sensitized stainless steel have been observed. Secondary phases include smectite clay, iron silicates, and brockite. Actinides, except neptunium, concentrate into stable secondary phases. The release of actinides is then controlled by the behavior of these phases
Original Title
Yucca Mountain Project
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Secondary Subject
Source
1995; 8 p; 97. annual meeting of the American Ceramic Society; Cincinnati, OH (United States); 30 Apr - 1 May 1995; CONF-950401--20; CONTRACT W-31109-ENG-38; Also available from OSTI as DE95013693; NTIS; US Govt. Printing Office Dep
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Report
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Conference
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