Near infrared absorption spectra of C60 radical cations and anions prepared simultaneously in solid argon
AbstractAbstract
[en] The codeposition of C60 vapor with excess argon and concurrent argon resonance radiation has produced strong new absorptions at 973 and 1068 nm in solid argon at 11 ± 1 K. A similar experiment with CCl4, added to serve as an electron trap, reduced the yield of the 1068 nm band with little effect on the 973 nm absorption. The 973 nm band is assigned to C60+ produced by photoionization and the 1068 nm band to C60- formed by electron capture. These identifications are in excellent agreement with glassy matrix, solution and photoelectron spectra. Preliminary magnetic circular dichroism (MCD) spectra of the 973 nm C60+ band have also been measured. Both the 1068 and 973 nm bands show a characteristic triplet structure which is tentatively attributed to the combined effects of spin-orbit and Jahn-Teller coupling
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Meeting of the American Physical Society; Indianapolis, IN (United States); 16-20 Mar 1992; CONF-920376--
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Journal Article
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Conference
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