Complex formation equilibria of some aliphatic α-hydroxycarboxylic acids. 3: A study of beryllium(II) complexes
AbstractAbstract
[en] Complex formation equilibria of beryllium(II) with five aliphatic α-hydroxycarboxylic acids, viz. glycolic (HL), lactic (HL), 2-hydroxyisobutyric (HL), L(+)-tartaric (H2L) and citric (H3L) acids, were studied by means of potentiometric (glass electrode) titrations at 25 deg. C in an ionic medium of 0.5 M NaClO4. The titrations were performed in a pH range in which precipitation did not occur. Glycolic and 2-hydroxyisobutyric acid complexation with beryllium(II) are described by the formation of three rather weak complexes, namely BeL+, BeL2 and Be3(OH)3L2+. Lactic acid was not found to form BeL2 species. The equilibrium model for tartaric acid constitutes of the three complexes mentioned above together with two deprotonated complexes Be(H-1L)24- and Be3(OH)3(H-1L). Citric acid was found to form also protonated and binuclear species prior to the formation of hydrolyzed complexes. The p,q,r analysis gave the following set of complexes: BeL-, BeL24-, Be2L2'2'2-, Be2H-2L24- and Be2H-3L25 stability constants for these complexes with their standard deviations are reported. (au) 23 refs
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