Structure and magnetic properties of Sm2(Fe1-xCox)16GaC and Sm2(Fe0.8Co0.2)16GaCy compounds
AbstractAbstract
[en] The effect of the substitution of Co for Fe on the formation, structure and magnetic properties of Sm2Fe16GaCy compounds were studied. Compounds with composition Sm2(Fe1-xCox)16GaC (x=0-0.3) and Sm2(Fe0.8Co0.2)16GaCy (y=0-2.0) were prepared by arc melting. X-ray diffraction shows that these carbides are almost single phase with the rhombohedral Th2Zn17-type structure. The unit cell volume (v) decreases monotonically with increasing Co concentration (x). The Curie temperature (Tc) increases with x from 592 K for x=0 to 816 K for x=0.3. The room-temperature saturation magnetization and the anisotropy field are 126.4 emu g-1 and 117 kOe respectively when the Co concentration x reaches 0.3. Addition of carbon results in the decrease of saturation magnetization and has a small effect on the Curie temperature and anisotropy field. (orig.)
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