Solution enthalpy of lithium perchlorate in diethyl ether, acetone, acetonitrile, dimethyl sulfoxide and effects of cycloaddition reactions acceleration
AbstractAbstract
[en] Integral solution enthalpies of lithium perchlorate in diethyl ether, acetonitrile, acetone and DMSO at 298,2 K are determined calorimetrically; they are equal to -6.2, -9.1, -15.9 and -18.0 kcal/mol correspondingly. For diethyl ether dependence of integral solution enthalpy on salt concentration within the range from 3 x 10-3 up to 5,6 mol/l is determined. Reducing exoeffect of salt dissolution in the ether from -6 up to -5 kcal/mol in the range of small concentrations (3 x 10-3 - 3 x 10-2 mol/l), the constancy of the effect in the 5 x 10-2 - 1.3 mol/l range and following smooth reducing exoeffect up to -3.2 kcal/mol at salt concentration 5.6 mol/l is pointed out
Original Title
Ehntal'pii rastvoreniyaperkhlorata litiya v diehtilovom ehfire, atsetone, atsetonitrile, dimetilsul'fokside i ehffekty uskoreniya reaktsij tsikloprisoedineniya
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18 refs., 1 fig., 3 tab.
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Journal Article
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