AbstractAbstract
[en] In previous studies, a conceptual tritium cleanup system was developed to remove tritium in various chemical forms from exhaust gases. This cleanup system differs from conventional ones employed at many facilities where tritium is handled in that tritium is removed as tritiated hydrogen molecules. In conventional systems, the tritium is removed in the form of water vapor. The present system consists of five main components: hydrogen separator, decomposition-processing vessel, hydrogen-absorbing vessel, circular pump, and buffer tank. The decomposition-processing vessel of the five main components was developed for this system in our laboratory. For the present study, it was assumed that the gas for processing was composed of hydrogen, methane, and helium. Some of the hydrogen and methane molecules were assumed to be tritiated, and helium was added to maintain a steady flow of gas through the stages of processing in the cleanup system. The performance of the tritium cleanup system was examined by computer-based simulation with simulated exhaust gas. To monitor removal of tritium from the exhaust gas, the partial pressures of hydrogen and methane were examined in a series of performance tests by computer simulation. Results indicate that the partial pressure of hydrogen underwent a characteristic change with two bend points, even though the partial pressure of methane continued to decrease steadily. The time positions of the bends and time interval between the two bend points on the curve of hydrogen partial pressure were investigated under various conditions in relation to component fraction and gas volume. The first bend appears to correspond to the completion of one cycle of processing and the second bend may correspond to the period where helium becomes the dominant determinant of pump speed. Both bends were observed at longer times, and the time interval between both bends increased as the amount of gas to be processed increased. Similarly, the second bend was observed at longer times, and the time interval between both bends increased with methane percentage. The results suggest that some features of exhaust gas can be estimated by inspecting both bend points, because the positions of the bend points and the time interval between them provided information about exhaust gas components and volume. (orig.)
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Source
Forschungszentrum Karlsruhe GmbH Technik und Umwelt (Germany); 327 p; 2007; [1 p.]; ISFNT-8: 8. international symposium on fusion nuclear technology; Heidelberg (Germany); 30 Sep - 5 Oct 2007; Available from TIB Hannover
Record Type
Miscellaneous
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Conference
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Descriptors (DEI)
Descriptors (DEC)
ALKANES, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CHEMICAL REACTIONS, DISPERSIONS, ELEMENTS, FLUID FLOW, FLUIDS, GASEOUS WASTES, GASES, HYDROCARBONS, HYDROGEN COMPOUNDS, HYDROGEN ISOTOPES, ISOTOPES, LIGHT NUCLEI, NONMETALS, NUCLEI, ODD-EVEN NUCLEI, ORGANIC COMPOUNDS, PHYSICAL PROPERTIES, RADIOISOTOPES, RARE GASES, SIMULATION, THERMODYNAMIC PROPERTIES, TRITIDES, TRITIUM COMPOUNDS, WASTES, YEARS LIVING RADIOISOTOPES
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