Reducing plant radiation fields by source term reduction - tracking cobalt and antimony to their sources at Gentilly-2
AbstractAbstract
[en] Gentilly-2 NGS is experiencing high radiation fields in the fuelling machine vaults. These high fields make maintenance outages more expensive and their management more complicated. As part of the station refurbishment project, a task group was created to identify the cause of the high fields and make recommendations to prevent their reoccurrence in the second (post-refurbishment) operating cycle. To identify the root cause of the problem, the task group decided to analyse the primary heat transport system (PHTS), the fuel handling system and their inter-relation. Gentilly-2 has had to manage a unique (to CANDU) problem arising from antimony released from the main heat transport pump seals. Antimony deposits on in-core surfaces, becomes activated, and subsequently can be released, especially under oxidizing coolant conditions. It then becomes incorporated into the magnetite deposits on PHTS piping, including the steam generators and inlet feeders. Gentilly-2 has focused a great deal of effort on managing antimony over the last 15 years. As a result of these initiatives, radioantimony fields have been quite effectively managed since 1997, resulting in a decrease in their relative contribution to the total fields. The decrease in radioantimony fields highlighted the significant contribution of 60Co cobalt activity; the high levels of both radioantimony and 60Co differentiate Gentilly-2 from other CANDU 6 plants. Two types of 59Co sources are present in the CANDU PHTS. High surface area materials such as steam generator tubes and feeder pipes contain trace concentrations of 59Co as an impurity, which can be released by corrosion. Low surface area materials such as Stellites contain high concentrations of 59Co that can be released as either corrosion or wear products. After assessing potential cobalt sources, the task group concluded that PHTS materials were not likely the origin of the high 60Co fields. The major PHTS components identified as cobalt sources have the same specifications at Gentilly-2 as at other CANDU 6 plants. Consequently, the task group revisited operating and maintenance practices, going back through station operating history to identify operational practices that could have lead to increased 59Co release and/or 60Co production. The focus rapidly moved to the fuel handling system, as it had long been suspected, but never proven, that the Stellite ram balls were a major source of 59Co; the fuelling machines provide a direct route for the introduction of corrosion or wear products into the reactor core. Data on the gamma fields measured in the fuelling machine D2O supply room from 1995 to the present were reviewed. Water samples were taken and chemically analysed. The results confirmed the presence of 59Co, probably generated by the wear and corrosion of the Stellite ram balls, and also confirmed the presence of antimony in the system. As part of the task group program, γ-spectrometry was performed in the course of a refuelling cycle. The results showed that variations in the general radiation fields observed in the fuelling machine D2O supply room resulted from variations of the 122Sb and 124Sb concentrations in the process water. The presence of 122Sb (t1/2 3.2 d) suggested that the antimony was recently released from the reactor core. 60Co was also detected but the level was constant; 59Co from the ram balls is invisible to γ-spectrometry before it is activated to 60Co. Remedial actions were implemented in mid-July, 2004. Shortly after, a significant reduction in the radiation fields in the Gentilly-2 fuelling machine D2O supply room was confirmed. During an unplanned outage in December 2004, a decrease in fields, in particular those due to 60Co and radioantimony, was found at the reactor face. Activity monitoring scheduled for the 2005 annual outage should confirm if the source of the abnormally high fields has finally been identified. This presentation will describe the task force program, the remedial actions taken and the benefits achieved. This work, originally initiated to improve post-refurbishment operations, may bring benefits earlier than expected. (author)
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Canadian Nuclear Society, Toronto, Ontario (Canada); 79.9 Megabytes; ISBN 0-919784-83-6; ; 2006; [13 p.]; 7. CNS international conference on CANDU maintenance. Proceedings; Toronto, Ontario (Canada); 20-22 Nov 2005; Available from the Canadian Nuclear Society, Toronto, Ontario (Canada); 5 refs., 3 tabs., 6 figs.
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Miscellaneous
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Conference
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