Fast method of XANES data collection suitable for oxidation state mapping
AbstractAbstract
[en] XANES has been recently used for the determination of oxidation states of actinides in environmental samples. To obtain reliable results, however, a sufficiently long counting time at every probing energy and a large number of experimental points per XANES spectrum are required, due to the complex mathematical model used to fit the measured spectrum. This makes micro-mapping difficult, since the time required for data collection becomes unacceptably long. A simplified model for data collection and evaluation is presented. Its effectiveness has been tested by measuring the distribution of Pu oxidation states in a 'hot' particle coming from a nuclear weapon test site. (author)
Primary Subject
Source
MARC VIII: Methods and applications of radioanalytical chemistry. Part 2; Hawaii (United States); 5-10 Apr 2009; 20 refs.
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Radioanalytical and Nuclear Chemistry; ISSN 0236-5731; ; CODEN JRNCDM; v. 282(2); p. 355-359
Country of publication
Descriptors (DEI)
Descriptors (DEC)
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue