Monazite as a suitable actinide waste form
AbstractAbstract
[en] The conditioning of radioactive waste from nuclear power plants and in some countries even of weapons plutonium is an important issue for science and society. Therefore the research on appropriate matrices for the immobilization of fission products and actinides is of great interest. Beyond the widely used borosilicate glasses, ceramics are promising materials for the conditioning of actinides like U, Np, Pu, Am, and Cm. Monazite-type ceramics with general composition LnPO4 (Ln = La to Gd) and solid solutions of monazite with cheralite or huttonite represent important materials in this field. Monazite appears to be a promising candidate material, especially because of its outstanding properties regarding radiation resistance and chemical durability. This article summarizes the most recent results concerning the characterization of monazite and respective solid solutions and the study of their chemical, thermal, physical and structural properties. The aim is to demonstrate the suitability of monazite as a secure and reliable waste form for actinides. (orig.)
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136 refs.
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Journal Article
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Zeitschrift fuer Kristallographie. Crystalline Materials; ISSN 2194-4946; ; v. 228(3); p. 113-123
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Descriptors (DEI)
CERAMICS, CERIUM PHOSPHATES, CRYSTAL STRUCTURE, DISSOLUTION, DYSPROSIUM PHOSPHATES, EUROPIUM PHOSPHATES, GADOLINIUM PHOSPHATES, LANTHANUM PHOSPHATES, MONAZITES, NEODYMIUM PHOSPHATES, PHYSICAL RADIATION EFFECTS, PRASEODYMIUM PHOSPHATES, SAMARIUM PHOSPHATES, SOLID SOLUTIONS, TERBIUM PHOSPHATES, WASTE FORMS
Descriptors (DEC)
CERIUM COMPOUNDS, DISPERSIONS, DYSPROSIUM COMPOUNDS, EUROPIUM COMPOUNDS, GADOLINIUM COMPOUNDS, HOMOGENEOUS MIXTURES, LANTHANUM COMPOUNDS, MATERIALS, MINERALS, MIXTURES, NEODYMIUM COMPOUNDS, OXYGEN COMPOUNDS, PHOSPHATE MINERALS, PHOSPHATES, PHOSPHORUS COMPOUNDS, PRASEODYMIUM COMPOUNDS, RADIATION EFFECTS, RADIOACTIVE MATERIALS, RADIOACTIVE MINERALS, RADIOACTIVE WASTES, RARE EARTH COMPOUNDS, SAMARIUM COMPOUNDS, SOLUTIONS, TERBIUM COMPOUNDS, THORIUM MINERALS, WASTES
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