An evaluation of methods for measurement of pesticides in sorption experiments
AbstractAbstract
[en] The concentration of four pesticides (2,4-D, atrazine, phorate, and terbufos) in soil solution during sorption experiments was measured using UV spectrophotometry, Gas Liquid Chromatography (GLC), High Performance Liquid Chromatography (HPLC), and radiotracer technique. The presence of water soluble organic matter in soil solution interfered with the measurement of pesticide using the UV spectrophotometry. The use of GLC, HPLC, and radiotracer technique involving 14C gave a good estimate of the concentration of pesticide in soil solution. The pesticide remaining in soil can be quantitatively analyzed by extracting with a scintillation solution containing an organic solvent such as toluene or dioxane. Among the various centrifuge tubes glass tubes with Teflon caps sorbed negligible amount of pesticides and these tubes can be used for the sorption measurements
Primary Subject
Source
FAO/AGRIS record; ARN: US1997082727; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Communications in soil science and plant analysis; ISSN 0010-3624; ; v. 29; p. 369-380
Country of publication
Descriptors (DEI)
ATRAZINE, CARBON 14, CONCENTRATION RATIO, DIOXANE, ECOLOGICAL CONCENTRATION, EVALUATION, HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY, INSECTICIDES, LABELLING, ORGANIC MATTER, ORGANIC SOLVENTS, RESIDUES, SCINTILLATIONS, SOIL CHEMISTRY, SOILS, SORPTION, SPECTROPHOTOMETRY, SPECTROSCOPY, TEFLON, TOLUENE, TRACER TECHNIQUES, ULTRAVIOLET RADIATION
Descriptors (DEC)
ALKYLATED AROMATICS, AROMATICS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CARBON ISOTOPES, CHEMISTRY, CHROMATOGRAPHY, DIMENSIONLESS NUMBERS, ELECTROMAGNETIC RADIATION, EVEN-EVEN NUCLEI, FLUORINATED ALIPHATIC HYDROCARBONS, HALOGENATED ALIPHATIC HYDROCARBONS, HERBICIDES, HETEROCYCLIC COMPOUNDS, HYDROCARBONS, ISOTOPE APPLICATIONS, ISOTOPES, LIGHT NUCLEI, LIQUID COLUMN CHROMATOGRAPHY, MATERIALS, MATTER, NONAQUEOUS SOLVENTS, NUCLEI, ORGANIC COMPOUNDS, ORGANIC FLUORINE COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, ORGANIC POLYMERS, PESTICIDES, PETROCHEMICALS, PETROLEUM PRODUCTS, PLASTICS, POLYETHYLENES, POLYMERS, POLYOLEFINS, POLYTETRAFLUOROETHYLENE, RADIATIONS, RADIOISOTOPES, SEPARATION PROCESSES, SOLVENTS, SYNTHETIC MATERIALS, YEARS LIVING RADIOISOTOPES
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