AbstractAbstract
[en] An investigation was made on a hydrogen getter material (DPPE) to determine its radiation stability. Such material has potential for nuclear industry applications. The material is composed of 75 percent of an unsaturated organic compound (1,6-diphenoxy-2,4-hexadiyne) and 25 percent catalyst (5 percent palladium on calcium carbonate). The radiation stability of this material and of the hydrogenated product was determined by exposing them to gamma radiation in air and vacuum and analyzing for radiolysis products and hydrogen capacity. The major products formed were phenol and carbon dioxide. Numerous solid compounds were also formed in much smaller yields. Product yields were much larger in air than in vacuum. Hydrogen uptake curves showed that the hydrogen capacity decreased appreciably after an absorbed dose of about 108 rads, and that irradiation is more detrimental in air than in vacuum. [For SI (metric) use: rads have been replaced by grays (Gy) and 1 gray = 1 joule per kilogram, and 108 rads = 1 megajoule per kilogram.]
Original Title
Dimerized phenyl propargyl ether containing Pd on CaCO3 catalyst
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Secondary Subject
Source
18 Oct 1976; 8 p; Available from NTIS. $4.00.
Record Type
Report
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Descriptors (DEC)
ALKALINE EARTH METAL COMPOUNDS, CALCIUM COMPOUNDS, CARBON COMPOUNDS, CARBONATES, CHEMICAL REACTIONS, DECOMPOSITION, ELECTROMAGNETIC RADIATION, ELEMENTS, IONIZING RADIATIONS, METALS, NONMETALS, ORGANIC COMPOUNDS, ORGANIC OXYGEN COMPOUNDS, OXYGEN COMPOUNDS, PLATINUM METALS, RADIATION EFFECTS, RADIATIONS, TRANSITION ELEMENTS
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