Generally the consolidation of multiple countries into a larger unified country involves violent conflict in the first place.
Without violence, or the threat of it somewhere in the picture, the elites of the smaller countries would be content with the status quo and would have no reason to consider merger.
Also, unification in a durable way often involves rationalisation and unification of popular language and culture, to ensure that the whole of society can work easily together and to ensure that former elites vanquished by violence cannot continue to circle their wagons around a separate existence.
Again, without overwhelming violence or threat, the masses of the originating countries would usually be content with the status quo - not necessarily because they oppose the alternative on its merits, but because the act of change itself is expensive to undertake, requiring either complicated transitional arrangements, or else sudden alienation of the extant adult generation steeped in the old ways. This is why losing a big war is often psychologically important in preparing a population for this change, because losing a war means losing confidence that the old ways are sufficient for survival.
To secede then usually involves another round of overpowering violence, unless the central state of the unified country is exceptionally weak and moribund.
Creating impetus for secession also often involves prior maladministration or excessive violence towards the seceding group by the central state in the first place, or it might involve incomplete merger in the first place (where language and culture were not properly broken open and united).
I think there would have to be very unusual circumstances where secession is not only followed by reunification, but that the reunification is a thoroughly peaceful one (especially if "peaceful" meant without some kind of perceived threat of future violence, even if no violence was actually observed).