Happy to share our latest work published in the International Journal of Hydrogen Energy, titled "Novel Ni–Ru/CeO2 catalysts for low-temperature steam reforming of methane".
Abstract
Upgrading of #biogas and #biomethane into #H2-rich streams by #steam_reforming is regarded as an effective strategy to reduce fossil fuel consumption contributing to the transition towards a #green_energy system. In this context, novel reactor configurations such as #membrane_reactors appear a promising route for #process_intensification, but they require novel catalysts more active at low temperatures, stable, and resistant to coke formation. In this work, we prepared and tested structured catalysts characterized by a low Ni content (7 wt%) and a very low Ru content (≤1 wt%) supported on ceria and deposed onto SiC monoliths. Catalysts were tested at low temperatures (<600 °C), i.e. at temperatures suitable for applications in Pd-based membrane reactors. Fresh and used catalysts were characterized by ICP-MS, N2 physisorption, XRD, TEM, SEM-EDS, XPS and H2-TPR to identify the physicochemical properties affecting the catalytic activity. The catalysts showed good activity towards methane reforming, stable performance, and good resistance to coke formation. Ruthenium affects both the intrinsic catalytic activity and the resistance to the inhibiting effect of steam on the reaction rate. This is related to improved redox properties due to the intimacy between the active metals and their strong-metal-support-interaction with the ceria. Finally, our catalysts show self-activation under reaction conditions, which is an interesting property for applications.
This is a joint work between CNR-STEMS and CNR ITAE, co-authored by Giovanna Ruoppolo, Almerinda Di Benedetto, Antonio Vita, Cristina Italiano, MINJU THOMAS, Giulia Sorbino, and myself and funded within the framework of PLUG-IN Project.
Available here (open access):
https://lnkd.in/d4P9TY3e
Professor at Hochschule Mannheim
1moInteresting work, and good luck for Your presentation 👍