Do sodium-ion batteries last long? 🔋
We at CARL are working on sodium-ion batteries, focusing on understanding the underlying degradation modes.
Check out our latest publication, “Failure Mode and Degradation Analysis of a Commercial Sodium-Ion Battery With Severe Gassing Issue”, which has just been released in Journal of Batteries & Supercaps.
🚀 💡 Takeaways:
Sodium-ion batteries offer a promising alternative to lithium-ion batteries by addressing ecological and economic challenges. However, to assess the applicability of these cells for different sectors, understanding aging behavior, including degradation modes, is crucial. This work presents a comprehensive aging analysis of 67 commercial sodium-ion batteries under various temperatures, C-rates, and depths of discharge. We analyzed the initial cell-to-cell variance and the aging trajectories regarding capacity fade and resistance increase. We demonstrated that the cycling rate does not significantly influence the aging trajectories, whereas smaller depths of discharge significantly reduce degradation. The degradation gradients for 25 °C and 40 °C were similar; for −10 °C, we observed rapid capacity fading that can be attributed to irreversible sodium plating. Furthermore, we identified the degradation modes for four different aging categories. Since some aging tests stopped due to gas-induced current interrupt device triggering at low current rates and states of charge, we proposed two hypotheses for the gassing under specific conditions, suggesting inadequate gas consumption in cathode-electrolyte side reactions or solid electrolyte interphase instability as potential causes. Overall, this work provides a valuable in-depth analysis of the aging behavior of a commercial sodium-ion battery as a function of temperature, C-rate, and depth of discharge, with data made available for further research.
📊 Download: https://lnkd.in/eZ_bh_kX
We at CARL congratulate Bowen Qian to his great work he conducted during his bachelor thesis!
Many hours he prepared the cells for testing and conducted many cell tests, enabling further data analysis!
We at CARL thank Matthieu Dubarry for the collaboration! This work is a great example of international cooperation on international level, bringing together expertise from the other side of the world! 🌎
Special thanks to Sebastian Klick and Matthieu Dubarry for the comprehensive analysis of all the data!
We thank the Bundesministerium für Bildung und Forschung (03XP0302C) for funding.
We thank the Federal Ministry for Economic Affairs and Climate Action (3EI6106D) for funding.
Thanks to all authors, Sebastian Klick, Hendrik Laufen, Moritz Fabian Schütte, Bowen Qian, Katharina Lilith Quade, Christiane Rahe, Matthieu Dubarry and Dirk Uwe Sauer.
And special thanks to Christiane Rahe, and Dirk Uwe Sauer for supervision and providing the foundation enabling such research at CARL!
#battery #sodiumion #aging #ISEA #CARL #RWTH