[en] Highlights: • Average EF for total-IVOCs from the mixed fleets of vehicles is 24.9 ± 7.8 mg/(km·veh) inside the tunnel. • EFs of total-IVOCs are affected significantly by the fleet composition. • Up to 86% of SOAFP is from IVOCs, while EFs of IVOCs are comparable to that of VOCs. Real-world vehicle emission factors (EFs) for the total intermediate volatile organic compounds (total-IVOCs) and volatile organic compounds (VOCs) from mixed fleets of vehicles were quantified in the Yangtze tunnel in Shanghai. Relationships of EFs of IVOCs with fleet compositions and vehicle speed as well as secondary organic formation potentials (SOAFPs) from IVOCs and VOCs were studied. Multiple linear regression (MLR) was used to estimate EFs of total-IVOCs for gasoline and diesel vehicles. IVOCs were classified into unresolved complex mixtures (unspeciated cyclic compounds and branched alkanes (b-alkanes)) and speciated targets (11 n-alkanes and ten polycyclic aromatic hydrocarbons (PAHs)). The results showed that the average EF of total-IVOCs was 24.9 ± 7.8 mg/(km·veh), which was comparable to that of VOCs. Unspeciated cyclic compounds and b-alkanes dominated the main composition (~77% and ~19%), followed by n-alkanes (~4%) and PAHs (~1%). EFs of IVOCs showed a significant, positive relationship with diesel vehicle fractions (p < 0.05). EFs of IVOCs dropped notably with the decrease of the diesel vehicle fractions. SOAFP produced by the total organic compounds (IVOCs + VOCs) was 8.9 ± 2.5 mg/(km·veh), in which up to 86% of SOAFP was from IVOCs. Estimated EFs of total-IVOCs for gasoline vehicles and diesel vehicles were 15.3 and 219.8 mg/(km·veh) respectively. Our results demonstrate that IVOCs emitted from diesel vehicles are the main emission sources under real world conditions and significant contributions of IVOCs emissions to SOA formation is evident, which indicates the necessity of making control policies to reduce IVOCs emissions from vehicles.

[en] Highlights: • Intensive surveys on catering industry information performed in two Chinese cities • Survey data help establish a national emission inventory of catering industry. • A significant correlation observed between vegetable oil consumption and emissions. • This correlation indirectly verifies by the rationality of the inventory. • This relation useful for dynamically updating emission inventory of catering sector Catering oil fumes are a major hazard to human health. In particular, the typical Chinese cooking style is characterised by a high temperature frying process that produces high levels of cooking oil fumes. However, limited data relating to this sector mean that national emission inventory data specific to the catering service industry do not exist. To address above deficiency and thus to establish the inventory of a city, or a province, or even a country, a door-to-door survey campaign was launched in the Chinese cities of Heze and Linfen to determine the structure of local catering industries. Data revealed that the number of catering businesses per 10⁴ people was 17 ± 4. Of these, 3.0 ± 1.4, 15.0 ± 1.4, and 82.0 ± 0.0% were classified as large, medium, and small enterprises, respectively. Furthermore, the installation rates of fume purifiers were 74 ± 13, 66 ± 9, and 51 ± 14% for large, medium, and small enterprises, respectively, with net removal efficiencies of 63 ± 11, 50 ± 7, and 31 ± 8%, respectively. This information was extrapolated across all provincial regions of China to construct a provincial and national emission inventory. In 2017, China's national catering industry released approximately 34 kt of volatile organic compounds (VOCs), 38 kt of particulate matter with a diameter less than 2.5 μm (PM_2.5), 48 kt of particulate matter with a diameter less than 10 μm (PM₁₀), 1 kt of black carbon (BC), and 27 kt of organic carbon (OC). A significant correlation was observed between vegetable oil consumption and emissions (e.g., for VOCs, y = 14.94 x + 76.50, R² = 0.87, where y is VOCs emissions and x is vegetable oil consumption), indirectly corroborating the rationality of the inventory. Moreover, this correlation provides the potential for a dynamic inventory based on vegetable oil consumption. Future studies are proposed to address more influential factors to improve the reliability of the national inventory and refer to big data, rather than door-to-door investigation, to identify the amount of catering service businesses in a region.

[en] The review article “Emergence and fate of cyclic volatile polydimethylsiloxanes (D4, D5) in municipal waste streams: Release mechanisms, partitioning and persistence in air, water, soil and sediments” by Surita and Tansel covers a relevant topic, but there are several serious issues with this paper. The inappropriate handling of data gathered from various sources has resulted in a flawed dataset. In addition, the authors performed several erroneous or meaningless calculations with the data. Their dataset leads to incorrect and misleading interpretations and should not be used

[en] Highlights: • Ion mobility coupled to gas chromatography (GC-IMS) enables booster control in table tennis. • Characteristic VOC patterns of table tennis coverings and from boosters can be differentiated. • Quantitative and selective determination of relevant compounds by calibration. • Short analysis time (1–2 min) using mobile GC-IMS allows booster monitoring on-site. • This analytical tool GC-IMS could help keeping sports fair and equitable. In all professional sports, performance pressure is high at the top level. Therefore, rules are defined and controlled to keep sports fair in accordance e.g. with the Agenda 21 of the International Olympic Committee. However, it’s about money and honour and as a consequence it is obvious that the athletes will go to the limits at all levels or even beyond. This is not only true for performance-enhancing substances to improve the physical capacity but – when sports equipment is involved – also for their optimisation. Thus, rules and related controls are necessary with regard to fairness between competitors but also with regard to their health when chemicals are involved. In table tennis, such chemicals (so-called boosters) are used occasionally – but against the rules – to improve the performance of the rackets. In the present study, several boosters were analysed as well as numerous common racket coverings using ion mobility spectrometry coupled to gas-chromatographic pre-separation. After optimisation of sampling with regard to improving reproducibility, characteristic patterns of volatiles for booster compounds and for racket coverings with different characteristics were developed successfully. In particular, signals related to particular softening agents could be identified and detected even in the untreated coverings. The patterns of volatiles were found to be characteristic for the particular boosters investigated as well as for the particular coverings. Furthermore, those patterns enable a differentiation between booster and covering or – in other words – between rule-consistent racket coverings and rule violation by after treatment of the rubber with a booster. After adaptation of the entire procedure to realistic competition situations, the method could be used for proving an infringement against the prohibition of applying such compounds.

[en] Highlights: • Thousands of VOC data collected near Deepwater Horizon spill site are analyzed • Statistical evidence indicates that SSDI did indeed reduce worker exposure to VOC • Incidents of peak concentrations were reduced by ~6 to 19 fold by SSDI • Data suggest that a more prompt use of dispersant would further reduce VOC exposure Controversy remains on the use of Sub-Sea Dispersant Injection (SSDI) during the Deepwater Horizon (DWH) spill to minimize the exposure of responders on surface vessels to volatile organic compounds (VOC). Here, we use extensive evidence (>90,000 VOC measurements) collected near the oil well MC252 site during the DWH spill and demonstrate at a high level of statistical confidence that SSDI enhanced the safety and health conditions of the responders at the water surface through the reduction of airborne VOC concentrations in a dose-dependent manner. VOC levels on ships' decks were clearly diminished (p < 0.001) during subsea dispersant use, and incidents of peak concentrations (>50 ppm VOC) that could have been an immediate concern to worker health were reduced by a factor of ~6 to 19 when dispersants were delivered at the intended rate. SSDI thus played an important role in minimizing potential exposure to VOC, and should be embedded in guidelines and regulations for dispersant use.

[en] This paper describes a method of estimating emission fluxes of biogenic volatile organic compounds (BVOCs) based on the approach proposed by and the high-resolution Corine land-cover 2000 database (1 x 1 km resolution). The computed emission fluxes for the Czech Republic (selected for analysis as being representative of a heavily cultivated, central European country) are compared with anthropogenic emissions, both for the entire country and for individual administrative regions. In some regions, BVOC emissions are as high as anthropogenic emissions; however, in most regions the BVOC emissions are approximately 50% of the anthropogenic emissions. The yearly course of BVOC emissions (represented by monoterpenes and isoprene) is presented, along with the spatial distribution of annual mean values. Differences in emission distributions during winter (January) and summer (June) are also considered. - The amount of the biogenic VOCs emitted over the central Europe is comparable with the anthropogenic VOC emissions from this region.

[en] Highlights: • Rhododendron tomentosum volatiles (monoterpenes and sesquiterpenes) adsorb toand are re-emitted by neighbouring plants. • Mixing RT volatiles with 100ppb ozone changes the blend of the volatile bouquet by degrading some compounds. • Volatile degradation due to ozone affects re-emission from the surface of neighbouring plants. • Mixing RT volatiles with ozone does not affect the deterrent properties it conveys on neighbouring plants. The perennial evergreen woody shrub, Rhododendron tomentosum, confers associational resistance against herbivory and oviposition on neighbouring plants through passive adsorption of some of its constitutively emitted volatile organic compounds (VOCs). The adsorption process is dependent on transport of VOCs in the air. In polluted atmospheres, the VOCs may be degraded and adsorption impeded. We studied the effect of elevated ozone regimes on the adsorption of R. tomentosum volatiles to white cabbage, Brassica oleracea, and the oviposition of the specialist herbivore Plutella xylostella on the exposed plants. We found evidence for adsorption and re-emission of R. tomentosum volatiles by B. oleracea plants. Ozone changed the blend of R. tomentosum volatiles and reduced the amount of R. tomentosum volatiles recovered from B. oleracea plants. However, plants exposed to R. tomentosum volatiles received fewer P. xylostella eggs than control plants exposed to filtered air irrespective of whether R. tomentosum volatiles mixed with ozone. Ozone disrupts a volatile mediated passive plant-to-plant interaction by degrading some compounds and reducing the quantity available for adsorption by neighbouring plants. The change, however, did not affect the deterrence of oviposition by P. xylostella, suggesting that aromatic companion plants of Brassica crops may confer pest-deterring properties even in ozone-polluted environments.

[en] This paper describes the development and application of a multi-channel monitoring system for recording, processing, and analyzing volatile organic compound (VOC) levels discharged to the atmosphere from a walk-in hood in a hazardous waste management facility. The monitoring system consists of an array of PID (photo ionization detector) sensors and a networked control program that provides operational schematic diagram, performs data analyses, and illustrates real-time graphical displays. Furthermore, the system records potential worker exposures, exhaust filtration efficiency and environmental release levels. Multi-channel continuous monitoring of VOCs is successfully implemented during chemical bulking operations. It is shown that a real-time monitoring system is effective for early warning detection of hazardous chemicals and for predicting the performance of adsorption filters used for VOC removal. In addition, a connected local weather visualization system supports efforts to minimize potential health and environmental impacts of VOC emissions to surrounding areas

[en] Highlights: • Organic gas emission for different emission standard gasoline vehicles are provided. • IVOC emissions are mainly subject to emission standard, then driving cycle and fuel. • The mass fraction of IVOCs and OVOCs increased with stricter emission standards. Continuous tightening emission standards (ESs) facilitate the reduction of organic gas emissions from gasoline vehicles. Correspondingly, it is essential to update the emissions and chemical speciation of total organic gases (TOGs), including volatile organic compounds (VOCs), intermediate volatility organic compounds (IVOCs), CH₄, and unidentified non-methane hydrocarbons (NMHCs) for assessing the formation of ozone and secondary organic aerosol (SOA). In this study, TOG and speciation emissions from 12 in-use light-duty gasoline vehicle (LDGV) exhausts, covering the ESs from China II to China V, were investigated on a chassis dynamometer under the Worldwide Harmonized Light-duty Test Cycle (WLTC) in China. The results showed that the most effectively controlled subgroup in TOG emissions from LDGVs was VOCs, followed by the unidentified NMHCs and IVOCs. The mass fraction of VOCs in TOGs also reduced from 61 ± 9% to 46 ± 18% while the IVOCs gently increased from 2 ± 0.4% to 8 ± 4% along with the more stringent ESs. For the VOC subsets, the removal efficiency of oxygenated VOCs (OVOCs) was lower than those of other VOC subsets in the ESs from China IV to V, suggesting the importance of OVOC emission controls for relatively new LDGVs. The IVOC emissions were mainly subject to the ESs, then driving cycles and fuel use. The formation potentials of ozone and SOA from LDGVs decreased separately 96% and 90% along with the restricted ESs from China II-III to China IV. The major contributor of SOA formation transformed from aromatics in the VOC subsets for China II-III vehicles to IVOCs for China IV/V vehicles, highlighting that IVOC emissions from LDGVs are also needed more attentions to control in future.

[en] Highlights: ► A new bioassay for testing the toxicity of VOCs on groundwater fauna is presented. ► Results on the toxicity of toluene to Niphargus inopinatus are now available. ► Henry equilibrium needs to be considered when bioassays with VOCs are designed. ► Methodological aspects related to “difficult-to-test substances” are discussed. -- Abstract: A protocol was developed for testing the ecotoxicological effects of volatile organic compounds (VOCs) on groundwater invertebrates. Test substance volatility was addressed in a “closed from start to analysis”-design. Since manifestation of toxic effects may be delayed in ‘slower metabolizing’ organisms such as groundwater fauna, a time-independent (TI-) approach was adopted. Toluene was used as a model substance and its toxicity to the groundwater amphipod Niphargus inopinatus was assessed as an example. The method evaluation process considered various methodological issues such as partitioning of the toxicant between the water and the gas phase (Henry equilibrium), the possible depletion of oxygen in closed test vials, as well as microbial biodegradation of the test substance. For N. inopinatus, an LC₅₀,_14days of 46.6 mg L⁻¹ toluene was obtained. The ultimate LC₅₀ value was estimated at 23.3 mg L⁻¹ toluene. No oxygen depletion occurred in the test vials and Henry equilibrium was found to be established after 6 h. The new test system proposed now awaits broad practical application