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AbstractAbstract
[en] Thermal evaporated thin Sn-O films subjected to annealing treatments in air in the range 473-1173 K and in Ar in the range 473-773 K followed by annealings in air up to 1373 K were studied by CEMS (Conversion Electron Moessbauer Spectroscopy). Complementary Moessbauer and X-ray measurements were also performed on SnO powder that underwent the same series of annealings. The presence of the intermediate oxide Sn3O4 was detected. A temptative hyperfine characterization for the Sn2+ site in Sn3O4 is given. (orig.)
Secondary Subject
Source
Latin American conference on the applications of the Moessbauer effect (LACAME '90); Havana (Cuba); 29 Oct - 2 Nov 1990
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Journal Article
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Conference
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Country of publication
Reference NumberReference Number
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INIS IssueINIS Issue
AbstractAbstract
[en] TDPAC measurements were carried out on 111In-implanted α-Nb2O5 samples at room temperature, after isochronal annealings up to 1270 K in 200 mbar oxygen and up to 1070 K in 10-5 mbar, respectively. The observed hyperfine interactions were compared to point charge model calculations which predict 15 and 2 equivalent cation sites in α-Nb2O5 and NbO2. The data in each system could be reproduced with one antishielding factor β=Vzzexp/Vzzpc for all sites, i.e. β(Nb2O5)=19.2 and β(NbO2)=31.2, respectively. (orig.)
Secondary Subject
Source
8. international conference on hyperfine interactions; Prague (Czechoslovakia); 14-19 Aug 1989
Record Type
Journal Article
Literature Type
Conference; Numerical Data
Journal
Country of publication
ANGULAR CORRELATION, BETA DECAY RADIOISOTOPES, CHALCOGENIDES, CORRELATIONS, DATA, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, HEAT TREATMENTS, INDIUM ISOTOPES, INFORMATION, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MINUTES LIVING RADIOISOTOPES, NIOBIUM COMPOUNDS, NUCLEI, NUMERICAL DATA, ODD-EVEN NUCLEI, OXIDES, OXYGEN COMPOUNDS, PERTURBED ANGULAR CORRELATION, RADIOISOTOPES, TRANSITION ELEMENT COMPOUNDS
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue
Shitu, Jorge; Massolo, C.P.; Bibiloni, A.G.; Renteria, Mario; Desimoni, Judith
Eleventh workshop on nuclear physics at TANDAR, Buenos Aires, 23-26 August 19881989
Eleventh workshop on nuclear physics at TANDAR, Buenos Aires, 23-26 August 19881989
AbstractAbstract
[en] The TANDAR accelerator of the National Atomic Energy Commission has been used to obtain the non-conventional radioactive probe 100Rh embedded in α - Nb2O5 allowing the PAC study of the range of high electric field gradients in this semiconductor. A sintered oxide tablet, obtained from metallic Nb powder calcination in air at 1050deg C, was irradiated with a 100 MeV 12C6+ beam for 15 hours to produce the 100Rh probe through the reaction 93Nb (12C,5n) 100Ag → 100Pd → 100Rh. The PAC measurements show a non-homogenous distribution of the probes substituting the Nb in lattice sites of high electric field gradient. The range of low electric field gradients was studied using the probe 111In incorporated to the samples by diffusion. (Author)
[es]
El acelerador TANDAR de la Comision Nacional de Energia Atomica ha sido utilizado para obtener la poco convencional sonda radiactiva 100Rh embebida en α - Nb2O5, permitiendo asi el estudio por CAP del rango de altos gradientes en campo electrico a este semiconductor. Una pastilla sinterizada del oxido, obtenido a partir de polvo de niobio metalico calcinado en aire a 1050grados C, fue irradiada con un haz de 100MeV de 12C6+ durante 15 horas para producir la sonda 100Rh a traves de la reaccion 93Nb (12C,5n)100Ag → 100Pd → 100Rh. Las medidas CAP de las muestras asi obtenidas permiten observar una distribucion no-homogenea de las sondas reemplazando substitucionalmente al Nb en sitios de alto gradiente de campo electrico (gce) de la red. El rango de bajos gce fue estudiado usando la sonda 111In incorporada por difusion en las muestras. (Autor)Original Title
Estudio por correlaciones angulares perturbadas del Nb2O5 en su fase α
Primary Subject
Source
Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Dept. de Fisica; 299 p; 1989; p. 247-260; Workshop on nuclear physics; 11. Reunion de trabajo en fisica nuclear; Buenos Aires (Argentina); 23-26 Aug 1988; Also available from Comision Nacional de Energia Atomica, Buenos Aires (AR)
Record Type
Miscellaneous
Literature Type
Conference; Numerical Data
Report Number
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue
AbstractAbstract
[en] The Time Differential Perturbed Angular Correlation has been successfully applied to the localized properties study in semiconductor materials. From the electrical quadrupolar hyperfine interactions determination and its comparison with results obtained from a point charge model, the defects were identified as oxygen vacancies non-homogeneously distributed in the sample. The results reveal a well-defined position of the Mo-surroundings defects. (Author)
[es]
Por su caracter extremadamente microscopico, la tecnica de las Correlaciones Angulares Perturbadas Diferenciales en el Tiempo (TDPAC) ha sido exitosamente empleada para estudiar propiedades localizadas en materiales semiconductores. Se presenta aqui una investigacion utilizando la tecnica TDPAC, sobre MoO3 empleando la sonda 99Mo-→β-99Tc.La irradiacion de MoO3 con neutrones provee a la vez la sonda y los centros de color debidas a las vacancias de oxigeno. Las medidas fueron realizadas a temperatura ambiente luego de recocidos en vacio y en aire. Los tratamientos en aire conducen a la recuperacion completa de la muestra, mientras que despues de los tratamientos en vacio se observa todavia la permanencia de defectos. A partir de la determinacion de las interacciones hiperfinas cuadrupolares electricas y de su comparacion con resultados obtenidos por un modelo de cargas puntuales, los defectos fueron identificados como vacancias de oxigeno distribuidas no homogeneamente en la muestra. Los resultados revelan una posicion bien definida de los defectos en el entorno del Mo. (Autor)Original Title
Vacancias de oxigeno en trioxido de molibdeno estudiadas mediante el empleo de una tecnica hiperfina
Primary Subject
Source
Asociacion Fisica Argentina, Rosario (Argentina); 397 p; 1990; p. 252-254; Asociacion Fisica Argentina; Buenos Aires (Argentina); 74. Meeting of the Argentine Physical Association; 74. Reunion de la Asociacion Fisica Argentina; San Luis (Argentina); 9-12 Oct 1989
Record Type
Miscellaneous
Literature Type
Conference
Report Number
Country of publication
ANGULAR CORRELATION, BARYONS, CHALCOGENIDES, CORRELATIONS, CRYSTAL DEFECTS, CRYSTAL STRUCTURE, ELECTRIC CHARGES, ELEMENTARY PARTICLES, ELEMENTS, FERMIONS, HADRONS, MOLYBDENUM COMPOUNDS, NONMETALS, NUCLEONS, OXIDES, OXYGEN COMPOUNDS, PERTURBED ANGULAR CORRELATION, POINT DEFECTS, TRANSITION ELEMENT COMPOUNDS
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Related RecordRelated Record
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AbstractAbstract
[en] The time-differential perturbed angular-correlation technique is applied to study stoichiometric and reduced molybdenum trioxides. Hyperfine characterization of 111Cd-probes substitutionally replacing Mo in the perfect crystalline lattice is presented. The trapping of doubly ionized oxygen vacancies in the most weakly bond site of the cation next neighbour is revealed by measurements in reduced MoO3. (author)
Secondary Subject
Record Type
Journal Article
Journal
Country of publication
ANGULAR CORRELATION, BETA DECAY RADIOISOTOPES, CADMIUM ISOTOPES, CHALCOGENIDES, CHEMICAL REACTIONS, CORRELATIONS, CRYSTAL DEFECTS, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, ENERGY-LEVEL TRANSITIONS, EVEN-ODD NUCLEI, HEAT TREATMENTS, INDIUM ISOTOPES, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MAXIMUM-LIKELIHOOD FIT, MINUTES LIVING RADIOISOTOPES, MOLYBDENUM COMPOUNDS, MULTIPOLES, NUCLEAR CASCADES, NUCLEI, NUMERICAL SOLUTION, ODD-EVEN NUCLEI, OXIDES, OXYGEN COMPOUNDS, PERTURBED ANGULAR CORRELATION, RADIOISOTOPES, STABLE ISOTOPES, TRANSITION ELEMENT COMPOUNDS
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue
Pasquevich, A.F.; Bibiloni, A.G.; Desimoni, J.; Lopes G, A.R.; Massolo, C.P.; Sanchez, F.H.
Proceedings of the 7. Latin American Symposium on Solid State Physics1981
Proceedings of the 7. Latin American Symposium on Solid State Physics1981
AbstractAbstract
[en] Published in summary form only
Original Title
Sobre la natureza de una interaccion bien definida en el sistema In/Ag/O
Source
Rio Grande do Sul Univ., Porto Alegre (Brazil); Centro Latino Americano de Fisica, Rio de Janeiro (Brazil); 116 p; 1981; p. 51; 7. Latin American Symposium on Solid State Physics; Gramado, RS (Brazil); 14-25 Sep 1981
Record Type
Miscellaneous
Literature Type
Conference
Report Number
Country of publication
BARYONS, BETA DECAY RADIOISOTOPES, CHEMICAL REACTIONS, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, ELEMENTARY PARTICLES, FERMIONS, HADRONS, INDIUM ISOTOPES, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MINUTES LIVING RADIOISOTOPES, MULTIPOLES, NUCLEAR REACTIONS, NUCLEI, NUCLEONS, ODD-EVEN NUCLEI, RADIOISOTOPES, TARGETS
Reference NumberReference Number
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AbstractAbstract
[en] In connection with a general study of the evolution of tin-oxygen thin films, we report here on the hyperfine interactions of 181Ta substitutionally replacing tin in the isolated phases SnO and SnO2. For this purpose, pure SnO pressed powder and a thin SnO2 film were implanted with 181Hf. In both cases, unique quadrupole frequencies were found after thermal annealing treatments. The results indicate that the following hyperfine parameters: νQ=740.6(2.1) MHz, η=0.07(2) and νQ=971.5(1.9) MHz, η=0.72(1) characterize 181Ta and SnO and SnO2, respectively. (orig.)
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Journal Article
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AbstractAbstract
[en] The electric quadrupole coupling constants of the lowest excited 5/2-state in 197Hg have been measured by the e--γTDPAC method for the hosts Ti and Sn at room temperature and for Zn and Cd at various temperatures. The observed temperature dependences are approximately the same as those known for other impurities in the same host lattices. They are well described by a simple Tsup(3/2) relation. (Auth.)
Primary Subject
Secondary Subject
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Journal Article
Journal
Hyperfine Interactions; v.1(3); p. 217-225
Country of publication
CADMIUM, COUPLING CONSTANTS, DIFFERENTIAL PAC, ELECTRIC FIELDS, EXCITED STATES, HIGH TEMPERATURE, INTERNAL CONVERSION RADIOISOTO, LOW TEMPERATURE, MEDIUM TEMPERATURE, MERCURY 197, QUADRUPOLE MOMENTS, QUADRUPOLES, TEMPERATURE DEPENDENCE, TIN, TITANIUM, ULTRALOW TEMPERATURE, VERY LOW TEMPERATURE, ZINC
ANGULAR CORRELATION, BETA DECAY RADIOISOTOPES, CORRELATIONS, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, ELEMENTS, ENERGY LEVELS, EVEN-ODD NUCLEI, HEAVY NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MERCURY ISOTOPES, METALS, MULTIPOLES, NUCLEI, PERTURBED ANGULAR CORRELATION, RADIOISOTOPES, TRANSITION ELEMENTS
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AbstractAbstract
No abstract available
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Journal Article
Journal
Physics Letters. A; v. 45(6); p. 465-466
Country of publication
ANGULAR CORRELATION, ANGULAR MOMENTUM, CORRELATIONS, DAYS LIVING RADIOISOTOPES, ELECTROMAGNETIC RADIATION, ELEMENTARY PARTICLES, ENERGY LEVELS, EVEN-ODD NUCLEI, FERMIONS, INTERMEDIATE MASS NUCLEI, IONIZING RADIATIONS, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, LEPTONS, NUCLEI, PARTICLE PROPERTIES, PERTURBED ANGULAR CORRELATION, RADIATIONS, RADIOISOTOPES, STABLE ISOTOPES, TIN ISOTOPES
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AbstractAbstract
[en] The influence of particle sizes on the oxidation kinetics in annealed and 'as-rolled' silver base 1 at% tin alloys was investigated by Moessbauer spectroscopy. The results show that it is possible, by controlling the oxide particle size to modify the internal oxidation kinetics, indicating that the oxygen diffusion can be altered by that means
Source
Short note.
Record Type
Journal Article
Journal
Physica Status Solidi. A, Applied Research; ISSN 0031-8965; ; v. 89(1); p. K17-K21
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