Decambox, P.; Delorme, N.; Mauchien, P.; Moulin, C.
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Dept. de Chimie Appliquee et d'Etudes Analytiques1989
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Dept. de Chimie Appliquee et d'Etudes Analytiques1989
AbstractAbstract
[en] Sensitive spectroscopic methods for the determination of actinides and lanthanides in various media are required in the nuclear industry. Laser-Induced Time-Resolved Spectrofluorometry (LITRS) for several actinides and lanthanides at very low levels and thermal lensing (TL) for oxidation state characterization allow these determinations. The set-up of LITRS is presented. Spectra, limit of detections and lifetimes obtained for U, Cm, Am, Eu, Gd, Tb, Dy, Ce, Sm, Tm are shown. Detection limit as low as 5.10-12 M can be achieved. Examples of matrices encountered for the determination of uranium are given as well as comparison with mass spectrometry and alpha counting. The set-up of TL and performances obtained on plutonium as well as future developments are presented
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1989; 17 p; 2. International Conference on Analytical Chemistry in Nuclear Technology; Karlsruhe (Germany, F.R.); 5-9 Jun 1989
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Berthoud, T.; Delorme, N.; Delorme, P.; Iaremenko, M.
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Inst. de Recherche Technologique et de Developpement Industriel (IRDI)1989
CEA Centre d'Etudes Nucleaires de Fontenay-aux-Roses, 92 (France). Inst. de Recherche Technologique et de Developpement Industriel (IRDI)1989
AbstractAbstract
[en] We describe an energy dispersive X ray fluorescence apparatus equipped with a cylinder graphite monochromator developed in our laboratory. The graphite monochromator is inserted between the sample and the detector, it permits the selection of the fluorescence X radiation from the sample before collection by the Si-Li diode. Hence, the signal versus noise ratio of the fluorescence peak is increased and the limit of detection of our apparatus for uranium is 0.1 mg/l. This apparatus is perfectly adapted for the L rays of all the transuranium elements determinations. We also demonstrate the possibility of determination of uranium or plutonium in either aqueous or organic (TBP) phase. This apparatus is well adapted to control low levels of uranium and plutonium solutions originating from Purex process
[fr]
Nous decrivons un appareil de fluorescence X a dispersion d'energie avec monochromateur de graphite developpe et construit au laboratoire. Le monochromateur de graphite, element original de l'appareil, selectionne une partie de la fluorescence reemise par l'echantillon avant d'etre recueillie sur le detecteur. Le rapport signal/fond du pic de fluorescence correspondant a l'element analyse en sera ainsi augmente, la limite de detection accessible etant de l'ordre de 100 ppb pour l'uranium. Nous travaillons, avec cet appareil dans une gamme d'energie de 0 a 20 Kev, c'est-a-dire que nous avons la possibilite d'exciter l'ensemble des raies L des elements transuraniens. Nous montrons la faisabilite de dosage de l'uranium et du plutonium pour des concentrations allant de 0,1 mg/l a 500 mg/l dans des phases aqueuses ou organiques indifferemment. Cet appareil est donc bien adapte a la mesure de l'uranium, du plutonium a bas niveau de concentration dans le procede, il peut en outre etre facilement adaptable a la mesure de ces elements en ligne et en continuOriginal Title
'Fluorescence X a dispersion d'energie avec monochromateur de graphite (Application l'analyse de U, Pu, en phases aqueuse et organique)'
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1989; 120 p
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AbstractAbstract
[en] The understanding of the radionuclides behaviour in groundwater is of major interest for radioelement migration modelling near a nuclear waste repository. In the case of lanthanides and actinides in groundwater, speciation of a particular oxidation state and its detection at very low level are the principal conditions to understand these mechanisms. In this scope, an experimental apparatus is developed with a double simultaneous detection: The first one is based on the thermal lensing effect through the flowing cuvette after the chromatographic liquid column and assures a good sensitivity for non fluorescent oxidation state determination, the second one is based on laser induced fluorescence measured in the same cuvette at 90deg C of the first axis which is known to be one of the most sensitive technique. In this paper we discuss the experimental set-up, results obtained for Nd and U after separation and future developments on radioactive elements. (orig.)
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2. international conference on chemistry and migration behavior of actinides and fission products in the geosphere (Migration '89); Monterey, CA (USA); 6-10 Nov 1989
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Journal Article
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DYSPROSIUM COMPOUNDS, EUROPIUM COMPOUNDS, FLUORESCENCE, GADOLINIUM COMPOUNDS, GROUND WATER, IONS, LASER SPECTROSCOPY, LIQUID COLUMN CHROMATOGRAPHY, NEODYMIUM COMPOUNDS, OPTIMIZATION, QUALITATIVE CHEMICAL ANALYSIS, RADIOACTIVE WASTE FACILITIES, RADIONUCLIDE MIGRATION, SAMARIUM COMPOUNDS, SENSITIVITY, SIMULATION, TERBIUM COMPOUNDS, TRACE AMOUNTS, URANIUM COMPOUNDS, VALENCE
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Berthoud, T.; Delorme, N.; Moulin, C.
Chemistry and migration behaviour of actinides and fission products in the geosphere1987
Chemistry and migration behaviour of actinides and fission products in the geosphere1987
AbstractAbstract
[en] Published in summary form only
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Technische Univ. Muenchen, Garching (Germany, F.R.). Inst. fuer Radiochemie; Commission of the European Communities, Brussels (Belgium); 196 p; 1987; p. 44; International conference on chemistry and migration behaviour of actinides and fission products in the geosphere (Migration '87); Muenchen (Germany, F.R.); 14-18 Sep 1987; Available from Technische Univ. Muenchen, Garching (Germany, F.R.). Inst. fuer Radiochemie
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AbstractAbstract
[en] A fully automated double beam optical configuration for thermal lens absorption measurements is presented. This set-up includes two dye lasers controlled by a microcomputer with constant power capability for spectrum scanning, special optical arrangement for active solution studies, automatic positioning of the probe beam at the detector and a lock-in amplifier controlled by the microcomputer for data acquisition and treatment. Spectra of plutonium at different oxidation states together with their detection limits are presented. (orig.)
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International conference on chemistry and migration behaviour of actinides and fission products in the geosphere (Migration '87); Muenchen (Germany, F.R.); 14-18 Sep 1987
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Journal Article
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Conference
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ACTINIDE COMPOUNDS, AMPLIFIERS, CHEMICAL REACTIONS, CHLORINE COMPOUNDS, CONTROL SYSTEMS, DISPERSIONS, EQUIPMENT, HALOGEN COMPOUNDS, HOMOGENEOUS MIXTURES, HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, LASERS, MIXTURES, NITROGEN COMPOUNDS, ON-LINE SYSTEMS, OPTICAL PROPERTIES, OXYGEN COMPOUNDS, PHYSICAL PROPERTIES, SOLUTIONS, SPECTRA, SPECTROSCOPY, TRANSURANIUM COMPOUNDS
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Decambox, P.; Delorme, N.; Mauchien, P.; Moulin, C.
Second Karlsruhe international conference on analytical chemistry in nuclear technology1989
Second Karlsruhe international conference on analytical chemistry in nuclear technology1989
AbstractAbstract
[en] Published in summary form only
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Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.); 223 p; 1989; vp; 2. Karlsruhe international conference on analytical chemistry in nuclear technology; Karlsruhe (Germany, F.R.); 5-9 Jun 1989
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Benony, G.; Delorme, N.; Pichon, R.
Nuclear techniques in the exploration and exploitation of energy and mineral resources1991
Nuclear techniques in the exploration and exploitation of energy and mineral resources1991
AbstractAbstract
[en] The feasibility of in-line uranium determination using energy dispersive X ray fluorescence is demonstrated. The development and subsequent construction of a circulation tank are described. The uranium detection limit in a flux obtained using this technique is 0.5 mg/L. (author). 6 figs, 4 tabs
Original Title
Faisabilite d'une mesure en ligne de l'uranium par fluorescence X (raies L) a dispersion d'energie
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International Atomic Energy Agency, Vienna (Austria); Proceedings series; 627 p; ISBN 92-0-060091-3; ; 1991; p. 187-201; IAEA; Vienna (Austria); International symposium on nuclear techniques in the exploration and exploitation of energy and mineral resources; Vienna (Austria); 5-8 Jun 1990; IAEA-SM--308/27
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Book
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Regnaud, F.; Berthoud, T.; Delorme, N.; Drin, N.; Mauchien, P.; Moulin, C.; Remy, B.
Karlsruhe international conference on analytical chemistry in nuclear technology1985
Karlsruhe international conference on analytical chemistry in nuclear technology1985
AbstractAbstract
No abstract available
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Kernforschungszentrum Karlsruhe G.m.b.H. (Germany, F.R.); 223 p; 1985; p. 2; International conference on analytical chemistry in nuclear technology; Karlsruhe (Germany, F.R.); 3-6 Jun 1985; Published in summary form only.
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