AbstractAbstract
[en] Using regression analysis, analytical models were obtained for the functional dependences of the density, the electrical conductivity, and the refractive index of solutions containing HNO3 (0 to 3 moles/liter) and UO2 (NO3)2 (0 to 2 moles/liter) in the temperature interval 25-400C. The model errors were +-).07%, for the density, +/-1.5% for the electrical conductivity, and +/-0.02% for the refractive index. The possibility of obtaining the inverse dependences are demonstrated: for the acid and salt concentrations as a function of density, electrical conductivity and temperature, with model errors of +/-1%. These models may be used in methods for determining the composition of the given system for the results of measuring two properties at a known temperature. In this case, within the model error limits of +/-1%, concentrations may be determined on the order of 1-3 moles/liter in the presence of microcomponents with a total concentration up to 0.02 moles/liter
Source
Translated from Radiokhimiya (USSR); 25: No. 3, 325-329(May-Jun 1983).
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Journal Article
Journal
Soviet Radiochemistry; v. 25(3); p. 306-310
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AbstractAbstract
[en] Using regression analysis, analytical models have been obtained for the concentration dependence of density, electric conductivity and light refractive index of HNO3 solution from 0 to 3 mol/l and of UO2(NO3)2 solution from 0 to 2 mol/l in the temperature range from 25 to 40 deg C. The model errors made up for density +-0.07%, for electric conductivity +-1.5% and for light refractive index +-0.02%. The possibility to obtain the reverse dependences - for acid and salt concentrations as functions of density, electric conductivity and temperature with the model errors +-1% is also shown. The models can be used in the methods of the composition determination of the given system from the results of measurements of two properties at a known temperature. Then, in the limits of the model errors +-1%, the determination of concentration values of the order of 1 to 3 mol/l can be made in the presence of microcomponents at their summary concentration up to 0.02 mol/l
Original Title
Statisticheskoe opisanie svojstv sistemy HNO3-UO2(NO3)2 -H2O s pomoshch'yu uravneni regressii
Source
For English translation see the journal Soviet Radiochemistry (USA).
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Journal Article
Journal
Radiokhimiya; ISSN 0033-8311; ; v. 25(3); p. 325-329
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AbstractAbstract
[en] Equations of dependences of acid and salt concentrations on two parameters (density, electric conductivity or viscosity) and temperature are obtained using the regression analysis according to the earlier data on properties of the system: nitric acid-alkali metal salt - water at different temperatures. Errors of definitions are evaluated using the multiparametric method along with permissible microcomponent amounts (about 1% of macrocomponent amount: acids and salts), effect of errors of measurement of solution parameters and correlation coefficients between parameters. Errors concentration determination constitute MRSE+-2-5 rel.% for the systems with alkaline metal salt representing one of macrocomponets
Original Title
Izuchenie mnogoparametricheskogo metoda analiza trekhkomponentnykh azotnokislykh rastvorov
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Source
For English translation see the journal Soviet Radiochemistry (USA).
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AbstractAbstract
[en] The authors use regression analysis on previously accumulated data on properties of nitric acid-alkali metal salt-water systems at different temperatures to obtain equations for the dependences of the acid and salt concentrations on two parameters and temperature. The authors have estimated the error in determinations using the multiparameter method, the allowable amount of trace components, the effect of errors in the measurement of the solution parameters, and the correlation coefficients between the parameters
Primary Subject
Source
Cover-to-cover translation of Radiokhimiya (USSR).
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Journal Article
Journal
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AQUEOUS SOLUTIONS, CESIUM NITRATES, ERRORS, LITHIUM NITRATES, MATHEMATICAL MODELS, MULTI-PARAMETER ANALYSIS, NITRIC ACID, PH VALUE, POTASSIUM NITRATES, QUANTITATIVE CHEMICAL ANALYSIS, QUANTITY RATIO, REGRESSION ANALYSIS, SENSITIVITY, SODIUM NITRATES, TEMPERATURE DEPENDENCE, TRACE AMOUNTS, URANYL NITRATES
ACTINIDE COMPOUNDS, ALKALI METAL COMPOUNDS, CESIUM COMPOUNDS, CHEMICAL ANALYSIS, DISPERSIONS, HOMOGENEOUS MIXTURES, HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, LITHIUM COMPOUNDS, MATHEMATICS, MIXTURES, NITRATES, NITROGEN COMPOUNDS, OXYGEN COMPOUNDS, POTASSIUM COMPOUNDS, SODIUM COMPOUNDS, SOLUTIONS, STATISTICS, URANIUM COMPOUNDS, URANYL COMPOUNDS
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