AbstractAbstract
[en] Experimental measurements are presented of the far infrared fluorescence from a non equilibrium rotational distribution in the vibrational ground state of hydrogen chloride. This distribution persists for times long compared with the mean time between collisions and the rate of decay of the distribution is comparable to the timescale of macroscopic heat transport. (orig.)
Primary Subject
Source
14. European congress on molecular spectroscopy: Modern trends in spectroscopy (EUCMOS); Frankfurt am Main, Germany, F.R; 3 - 7 Sep 1979
Record Type
Journal Article
Literature Type
Conference; Numerical Data
Journal
Journal of Molecular Structure; ISSN 0022-2860; ; v. 61 p. 87-90
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AbstractAbstract
[en] 0pto-acoustic techniques have been used to measure vibrational energy relaxation in metyl halides and their mixtures with inert gases. Under certain conditions time-resolved measurements give direct evidence of a V-R-T relaxation channel parallel to he V-T relaxation channel. Comparison with infrared fluorescence data confirms this conclusion. (orig.)
Primary Subject
Record Type
Journal Article
Journal
Chemical Physics Letters; ISSN 0009-2614; ; v. 73(3); p. 429-432
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