Hydrogen-isotopic composition of some hydrous manganese minerals
AbstractAbstract
[en] Initial data on the hydrogen-isotopic compositions in hydrous Mn minerals from various occurrences fall in a wide range from -298 to -84per thousand, relative to SMOW. deltaD-values of todorokite and cryptomelane from Tertiary deposits show -89 and -150per thousand. 10 A-manganite and delta-MnO2 from deep-sea nodules have relatively restricted deltaD-values ranging from -96 to -84per thousand. The deltaD-values for manganese bog ores from recent hot springs show almost -105per thousand. It is recognized that the isotopic values obtained for the deep-sea nodules and recent bog ores are slightly different ranged. Manganite and groutite are unique in their hydrogen-isotopic compositions, having the most depleted deltaD-values ranging from -298 to -236per thousand. MnO(OH) minerals are more deuterium-depleted hydrous minerals than any other hydrothermal minerals from various ore deposits. Hydrogen-isotope fractionation factors between manganite and water were experimentally determined to be 0.7894, 0.7958 and 0.8078 at 1500, 2000 and 2500C respectively. The present experimental results indicate that if manganites were formed at temperatures below 2500C, under isotopic equilibrium conditions most of the manganite mineralization in the Tertiary manganese deposits must have precipitated from meteoric hydrothermal solutions. (Auth.)
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Chemical Geology; ISSN 0009-2541; ; v. 34(1-2); p. 43-52
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