Low temperature ion-nitriding of Fe-Mo-C sintered steels
AbstractAbstract
[en] The nitridability at low temperatures (723-773 K) of Fe-Mo-C sintered steels has been studied: the possibility to realize hardened surface layers of appropriate characteristics has been examined also to reduce surface microstructure alterations (e.g. decarburization) and size and shape variations which may occur for thermochemical treatments at higher temperatures. In a semi-industrial ion-nitriding plant Fe-Mo 1.5-C 0.3 (with martensitic matrix) and Fe-Mo 1.5-C 0.5 (with bainitic matrix) sintered steels have been ion-nitrided at temperatures included in the range 723/823 K and for treatment times of 4/24 h. As previously noticed, the first sintered steel, if ion-nitrided at 823 K for more than 8 h, presents a surface hardness of about 700 HV but also a sharp hardness fall (down to 450 HV) immediately beyond the compound layer owing to decarburization phenomena. Reducing the treatment temperature (773 K) this effect does not appear: the nitrided layer shows a regular hardness profile, with maximum hardness value of 720 HV and thickness of about 100 μm, and consists essentially of the Fe4N γ' cubic nitride and Fe2-3(C,N) ε hexagonal carbonitride. At the same time, the ion-nitriding treatment in the temperature range 723/823 K has been applied to the second sintered steel. In this case, no decarburization has been observed also for treatments at the highest temperature; the hardness profiles show a gradual decrease from 730 HV to the matrix value (350 HV), but the hardness depth results very limited also for treatment times of 24 h. (orig.)
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Source
3. European conference on advanced materials and processes (EUROMAT-3); 3. Conference Europeenne sur les Materiaux et les Procedes Avances; Paris (France); 8-10 Jun 1993
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Journal Article
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Conference
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Descriptors (DEI)
BAINITE, DECARBURIZATION, HARDNESS, ION IMPLANTATION, IRON NITRIDES, MARTENSITE, MICROHARDNESS, MICROSTRUCTURE, MOLYBDENUM ALLOYS, NITRIDATION, NITRIDES, SCANNING ELECTRON MICROSCOPY, SINTERED MATERIALS, SINTERING, STEELS, SURFACE HARDENING, TEMPERATURE DEPENDENCE, TEMPERATURE RANGE 0400-1000 K, X-RAY DIFFRACTION
Descriptors (DEC)
ALLOYS, CARBON ADDITIONS, CHEMICAL REACTIONS, COHERENT SCATTERING, CRYSTAL STRUCTURE, DIFFRACTION, ELECTRON MICROSCOPY, FABRICATION, HARDENING, IRON ALLOYS, IRON BASE ALLOYS, IRON COMPOUNDS, MATERIALS, MECHANICAL PROPERTIES, MICROSCOPY, NITROGEN COMPOUNDS, PNICTIDES, SCATTERING, SURFACE TREATMENTS, TEMPERATURE RANGE, TRANSITION ELEMENT COMPOUNDS
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