AbstractAbstract
[en] The first theoretical study of the effect of the final-state interaction on the initial core-hole lifetime is presented. The 4s-hole lifetime width of Sn metal is calculated by an ab-initio atomic many-body theory (Green's function method). When the final-state interaction in the 4p4d two-hole state, created by the 4s-1-4p-14d-1 εf super Coster-Kronig (CK) transition of the initial 4s hole, is explicitly taken into account, the ab-initio atomic many-body calculation of the 4s-hole X-ray photoelectron spectroscopy (XPS) spectrum of Sn atom can provide excellent agreement with experiment in both the 4s-hole energy and the 4s-hole lifetime width. Otherwise, the many-body calculation underestimates considerably the 4s-hole lifetime width. The 4p4d two-hole state interacts strongly with the 4d triple-hole state by the 4p-14d-1-4d-3 εf super CK transition. The interaction affects greatly the initial 4s-hole lifetime width
Source
S0368204802003067; Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Journal of Electron Spectroscopy and Related Phenomena; ISSN 0368-2048; ; CODEN JESRAW; v. 130(1-3); p. 7-17
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