Kinetics study of selective solvation of electrons in water--dimethyl sulfoxide mixtures
AbstractAbstract
[en] Dimethyl sulfoxide (DMSO) is known to solvate with difficulty anions including the electron and hence the addition of DMSO to a medium increases the anionic reaction rates. An attempt was made to study this effect in mixtures of H2O--DMSO for specific reactions of the solvated electron using the pulse radiolysis technique. To begin with we chose different solutes among those known as good scavengers of electrons, neutral ones, N2O, and positive and negative ionic ones (NO3- and H+). The experiments were carried out with a Febetron delivering 10-nsec pulses of 1.8-MeV electrons. The rate of disappearance of the solvated electron formed by the pulse was measured by direct observation of the decay absorption at 870 or 600 nm. The ultrapure products were used as supplied except for DMSO which was distilled before use
Original Title
Pulsed electron irradiation
Record Type
Journal Article
Journal
Journal of Physical Chemistry; v. 79(26); p. 3038-3040
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Descriptors (DEC)
ALKALI METAL COMPOUNDS, BEAMS, CHALCOGENIDES, CHEMICAL RADIATION EFFECTS, CHEMICAL REACTIONS, CHLORINE COMPOUNDS, DECOMPOSITION, ELEMENTARY PARTICLES, FERMIONS, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, IRRADIATION, KINETICS, LEPTON BEAMS, LEPTONS, NITRATES, NITROGEN COMPOUNDS, ORGANIC COMPOUNDS, ORGANIC SULFUR COMPOUNDS, OXIDES, OXYGEN COMPOUNDS, PARTICLE BEAMS, RADIATION EFFECTS, REACTION KINETICS, SODIUM COMPOUNDS, SULFOXIDES
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