In this paper an attempt has been made to elucidate the relationship between the formation of photochemical oxidants and the emission rate of the primary pollutants such as nitrogen oxides (NO
X) and reactive hydrocarbons (RH) over the Osaka Bay and its surrounding areas of Japan, by using a three-dimensional grid model. In Harima area, reduction in the primary pollutant emission led to simple decrease in the peak O
3 concentration, and OH and HO
2 radical concentrations. In Osaka area, unlike the Harima area, reduction in NO
X emission led to an increase in OH and HO
2 radicals concentrations, and conversely to an increase in O
3 concentration. It has also been found that the time of peak O
3 concentration would appear earlier with reduction in NO
X emission, and later with reduction in RH emission. Under meteorological calm condition, the variations of the time of appearance of peak O
3 due to the emissions reduction scenario are small. Sea breeze may be one of the important meteorological phenomena responsible for the transport of pollutants such as NO
X, RH, and also O
3 in the polluted coastal areas. These important results suggest that a method for a well-balanced reduction in both NO
X and RH emissions is essential for the improvement of air quality from photochemical pollution over the Osaka Bay and its surrounding areas of Japan.
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